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CAS 123-39-7 N-Methylformamide / NMF Used in Pesticide

N-Methylformamide (NMF) is a colorless, nearly odorless, organic compound with molecular formula CH3NHCHO, which is a liquid at room temperature. It is infinitely soluble in water. NMF is mainly used as a reagent in various organic syntheses with limited applications as a highly polar solvent.
NMF is closely related to other formamides, notably formamide and dimethylformamide (DMF). However, industrial use and production of NMF are far less than for either of these other formamides. DMF is favored over NMF as a solvent due to its greater stability. Annual production of NMF can be assumed to be significantly less than the production of either formamide (100,000 tons) or DMF (500,000 tons).
 
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Chemical and physical properties of N-methylformamide

density 1.011
Boiling point 199-201 ºC
Melting point -4 ºC
Molecular formula 2 H 5 NO
Molecular weight 59.067
Flash point 111 ºC
Precise quality 59.037113
PSA 29.10000
LogP -0.60
Appearance traits Transparent colorless liquid
Vapor pressure 0.8±0.3 mmHg at 25°C
Refractive index 1.431-1.433
Storage conditions

1. Packed in 200kg iron drum. Sealed storage to prevent leakage, avoid rain, exposure, severe impact and friction. Keep away from fire and heat sources. Class 1 flammable liquid, Dangerous Regulation No. 61152.

stability

1. Colorless transparent viscous oily liquid. It is soluble in water and can also dissolve inorganic salts. It is hygroscopic and easily decomposes in acidic or alkaline solutions. It smells of ammonia.

The chemical properties interact with hydrogen chloride to form two kinds of salts; HCONHCH3·HCl is produced in non-polar solvents; (HCONHCH3)2·HCl is produced when there is no solvent. It has almost no effect with sodium metal at room temperature. Hydrolysis occurs under the action of acid or alkali. The acidic hydrolysis rate is formamide>N-methylformamide>N,N-dimethylformamide. The alkaline hydrolysis rate is formamide-N-methylformamide>N,N-dimethylformamide.

2. Exist in mainstream smoke.


Water solubility miscible
IMG_3279(20200617-163238)

微信图片_20210909142552


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